No, not really. The closest you'll get to that is to give the Agent multiple login accounts, but use the same phone.
See, an Agent is skilled by an admin or supervisor, and those skills are assigned to CSQ's by an admin or supervisor. Nothing about that process allows the Agent to have a choice.
However, the "do's and dont's" of UCCX allow multiple Agents to share the same phone, just so long as they are not trying to use it at the same time. Think of an office with 24/7 coverage, and people sharing desks between shifts. This is totally valid.
So, in a way, you are creating new Agents, but for the purpose of having a different skill set, and thus servicing a different CSQ.
The Agent simply logs out of one, and into the other, to select which CSQ they want to serve. This will mess with reporting, because now all of their activities under one login will not completely capture the big picture.
Good luck.
EDIT: I should also mention, if you have a small call center, and only needed this to happen for like one person, you could just make them a supervisor of themselves, and then they can just adjust the skills as needed. But this does not work on a large scale at all.
Anthony Holloway
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