You will need to define a new network to represent the subnet between the ASA and ISA (this is a traditional DMZ). This could be private or public; unless you have a lot of public IP addresses that you can subnet down, this network is likely to be a private network. The ASA will therefore NAT all inbound and outbound traffic to/from ISA. You can then either NAT or route traffic through ISA to the internal network.
The key thing to remember is that the ASA will need to have all the NAT entries to provide the correct traffic flow AND also you will need to define ACLs to allow different types of outbound access, primarily, this will be ISA though...
Have a look at the following articles which give you a good feel of a back-to-back setup:
http://www.isaserver.org/tutorials/Configuring-Domain-Members-Back-to-Back-ISA-Firewall-DMZ-Part1.html