Depending on which method the pix is using for Authentication, you should be able to do this:
Option 1:
aaa authentication include | exclude authen_service if_name local_ip local_mask [foreign_ip foreign_mask] server_tag
Option 2:
aaa authentication match acl_name if_name server_tag
I know Option 2 works. In the ACL Option 2 refers to, you can include a deny statement before the permit statements. The deny statements tell the Pix which traffic not to authenticate. With the flexability of the ACL, you can tell it Specific Source/Destination IPs/Protocols/Ports.
There's some good examples at this location:
http://www.cisco.com/univercd/cc/td/doc/product/iaabu/pix/pix_sw/v_63/cmdref/ab.htm#wp1111727
Hope this helps,
peter