By definition, a MAB (MAC Authentication Bypass) username is the MAC address. The MAC address is used for the password with MAB, too.
To see a username to MAC or IP mapping with pxGrid, you need to have an actual username+password authentication and for that you must use a different EAP protocol (PEAP typically with AD).
I am not aware of EAP-PSK support for ISE so I don't know how it would work at all.
https://www.cisco.com/c/en/us/td/docs/security/ise/3-2/compatibility_doc/b_ise_sdt_32.html