Same Problem here. I've discovered all the access switches in the environment and they are "Managed" in Device Work Center. Previously we used CiscoWorks and that populated the Mac address, IP address, along with what switch the end host was connected to. That was very helpful for our Helpdesk in troubleshooting. Im now trying to setup the same thing in Prime. Looking at a individual switch the MAC would populate but nothing on IP Address.
Im at a loss. I've newly taken over the position of Network Analyst so maybe there is a licensing issue that we didnt get that im not aware of thats not bringing the ISE or LMS portion of Prime into play?