That's not what ILS is for, if you're using UDS for Jabber then you would need to configure your LDAP sync to:
A) Sync the other domain/sub-domain assuming it's part of the same forest
B) If different forests, perform a multi-forest integration
If you're not using LDAP sync, then you'd need to create all your users in both clusters for that to happen.
HTH
java
if this helps, please rate