Extended access control lists in the 2600, applied to inbound traffic to the router on the interfaces in question, will do what you want to do.
Basic sequence of the access list commands you would use follows.
1. Permit traffic (http) from source IPs on one LAN to destination IPs on the other, or to the Internet. Examples:
access-list 100 permit tcp eq 80
access-list 100 permit tcp eq 80 established
or
access-list 100 permit tcp any eq 80
access-list 100 permit tcp eq 80 any established
2. Permit traffic (smtp) from source IPs on one LAN to destination IPs on the other, or to the Internet. Examples:
access-list 100 permit tcp eq 25
access-list 100 permit tcp eq 25 established
or
access-list 100 permit tcp any eq 25
access-list 100 permit tcp eq 25 any established
3. Deny all other traffic and log it. Example:
access-list 100 deny ip any any log
You will probably find that there are other supporting protocols that also need to be permitted before you apply the blanket "deny" statement, for example, DNS for URL name-to-IP-address resolution. (Otherwise, you have to know where you want to get to on the internet by IP address.) So, put something like this in front of the last "deny" command:
access-list 100 permit udp any eq 53
The logs will show you what you're blocking. You can then investigate and determine whether you need more "permits".
To apply the access-lists to specific interfaces, go into interface configuration mode and run an ip access-group" command. Example:
interface Ethernet0/0
ip address
ip access-group 100 in
Don't forget to save your configuration, too, when you're done.
Remember, on Cisco access-lists if you don't put a blanket "deny" at the end of the list, there is an implicit one put in for you. And access-list permits and denys are processed in the order in which they are listed. Once an access-list command applies to the traffic in question, the appropriate action is taken and no further processing of the access-list for that particular traffic is done. So if you're trying to block something specific, make sure you do that _before_ you permit everyone else to access it; otherwise, it'll get permitted first, and will never get denied.
That's access control lists in a nutshell. For more detailed info, browse around and search Cisco's web site, there's plenty there to keep you busy reading and learning for a long time.
Hope this helps.
