Not quite sure i understand your requirement.
You have a client at the branch that are trying to connect to port 23 at the corporate end server?
But i thought you have site-to-site VPN connection between branch and corporate, wouldn't that already be a secure VPN between the 2 sites?
Not quite sure i understand why you would like to connect using AnyConnect when you already have site-to-site vpn between the 2 sites.