Hi @Gonzo1
I'd recommend you test the newer one in 2.0 first. As soon as you are comfortable with that and able to make you environment work with 2.0 you can upgrade the older one and then put them in cluster mode when both had 2.0 version.
This way there will be no down time for users.
ISE really takes a lot of time to upgrade and it is upgraded separately, first secondary then primary.
-If I helped you somehow, please, rate it as useful.-