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I finally able solve a huge issue after three days after taking support of Cisco.
I had a server 1 (10.33.206.11) placed in one of the interface on ASA (FWSM-6509) and another server 2 (10.33.193.140) in the inside zone directly connected through sw...
Peter and Aditya, There is no NATing done on this Fiewall as I said this is not internet facing firewall. its completely in intranet zone. The server 1 was accessible from the server placed and coming from outside interface but not from inside.