The radius settings for a specific NAD get configured and assigned here: Administration->Network Resources->Network Devices. You add the NADs that will use ISE for certain purposes such as radius, trustsec, tacacs+, etc. there. Edit one of the NADs you create and go to the RADIUS Authentication Settings. This is where you configure unique settings. As for the RADIUS protocol ports go here: Administration->System->Settings->Protocols->RADIUS->UDP Ports. Lastly, you can get the ISE IPs via CLI (show int g 0; show int g 1; etc.). HTH!