Heads Up :
The post you are writing will appear in a public forum. Please ensure all content is appropriate for public consumption. Review the employee guidelines for the community here.
Can you please define what you mean by "unsecure" sites?
If you mean websites which contains malware/spyware, then the answer is NO by using the ASA itself. You can either use CSC module, or redirect traffic to Scansafe cloud to get those blocks.