You want to protect credit card data with a firewall that is out of support and didn't get security updates for thousands of years? Well, good luck with your audits ... (yes, I'm overstating it a bit; still, you are putting your company at risk by operating an outdated security device).
Back to your problem. Inter VLAN routing is allowed out of the box on the PIX. All you need is:
- Configure a new interface for the new network.
- Configure Access-Control for the new network and the old networks to only allow the communication that is needed
- Based on your needs, configure NAT-rules to translate the traffic (if you have to based on PCI requirements or other means) or exempt your traffic from NAT.