Hello,
You can do it in the following way:
VPN:
access-list nat0 permit ip 10.0.0.1 255.255.255.0 172.16.0.0 255.255.255.0
nat (inside) 0 access-list nat0
And then just pat your host (or network):
nat (inside) 1 10.0.0.0 255.255.255.0
global (outside) 1 interface
nat0 will be evaluated only for accessing remote end.