No your ASA5520 can not upgrade directly from 8.0(2) to 9.1(x). Here is some information from Cisco documentation:
If you are upgrading from a pre-8.3 release:
– See the Cisco ASA 5500 Migration Guide to Version 8.3 and Later for important information about migrating your configuration.
– You cannot upgrade directly to 9.0 or later. You must first upgrade to Version 8.3 or 8.4 for a successful migration.
You can use this link to find additional details
http://www.cisco.com/c/en/us/td/docs/security/asa/asa91/upgrade/upgrade91.html
HTH
Rick
HTH
Rick