Hi Andrew,
Ok I haven't hard the priviledge to be in your shoes, but I think from what I know with the Active/Standby, all you need to do is change the IP address on the Active firewall, which replicates on the Standby remember that's why you have the Failover link, to replicate Configuration to the Standby firewall. Also you'll need to contact those you are having your VPN tunnel with to give them your new IP to update their tunnel-group xxx.xxx.xxx.xxx type ipsec-l2l, tunnel-group xxx.xxx.xxx.xxx ipsec-attributes. But please backup your previous configs just before you start doing the change! It's always go to err on the side of caution.
I hope this helps anyway.
BRGS
Teddy