Hello,
As commands are entered in the active ASA, the commands should be replicated on the standby unit. The following is mentioned in the configuration guide:
Command replication always flows from the active unit to the standby unit. As commands are entered on the active unit, they are sent across the failover link to the standby unit. You do not have to save the active configuration to Flash memory to replicate the commands.
http://www.cisco.com/en/US/docs/security/asa/asa82/configuration/guide/ha_active_standby.html#wp1079487
So changing the interface parameters on the active ASA should be replicated to the standby unit.
Changing the duplex or speed of the interface will not perform a shut/no shut on the interface, but it will interrupt traffic since the interface will try to detect the settings of the switchport it's connected to and renegotiate. For example, if the switchport is configured for auto duplex, and on the ASA you switch the duplex setting from full duplex to half duplex, a little time is needed for the switchport interface to negotiate to half duplex in order to match the ASA.
Therefore, it's probably best to make these changes after hours or during a maintenance window.
Hope this helps.