Yes, the router by default will callout the number in the sequence in which they are configured. Further we can configure the order (as seen below)
Router(config)#int dialer 1 (or even directly under the physical interface / if its a BRI/PRI then will not need dialer in-band))
Router(config-if)#dialer in-band
Router(config-if)#dialer string 12345
Router(config-if)#dialer string 67890
Router(config-if)#dialer string 13579
Router(config-if)#dialer order ?
last-successful <= Choose the last successful dial string first
round-robin <= Choose dial strings in round-robin order
sequential <= Choose dial strings in sequential order
For other configs on backup, please refer to:
http://www.cisco.com/pcgi-bin/Support/browse/psp_view.pl?p=Technologies:DDR&s=Implementation_and_Configuration
Thanks, Mak