Hi Quroo,
This is very simple. Nothing special. If you just want to create VLANs, however please let us know the business reasons behind the requirements and we shall be glad to advice you over the complete solution.
To create VLAN on any of these switches (assuming both are running on 12.3 IOS onwards) the following commands would do:
Swtich(config)#vlan 2
Swtich(config-vlan)#name Marketing
Switch(config-if)#ip address x.x.x.x y.y.y.y
Also for a detailed information on the 4500 series switch, you can visit the config guide at http://cisco.com/en/US/products/hw/switches/ps4324/products_configuration_guide_book09186a008062c520.html
Hope it helps.
Please rate if it helps.
Regards,
Wilson Samuel