that's an interesting challenge. Unfortunately, I didn't see any possibility using Cisco Router. I saw, however, an interesting approach in a blog where a guy used Linux as a router.
Linux has a command like this:
route add -net 2620:108:700f:: ::1 -reject
According to this guy, "Null routing will send an icmpv6 message back to the device telling them that the host is "unreachable" and the device can then fail over to using ipv4 (assuming you have a dual stack network running )"
I think he refers to ipv6 and not ipv4.
Here is the link for reference:
https://forums.he.net/index.php?PHPSESSID=g7k1iq0lkn8ghienuhd4qs264c&topic=3564.0
-If I helped you somehow, please, rate it as useful.-
Flavio Miranda