Normally the QoS is protocol based. That is, precedence is given to traffic based on type of protocol, like if it is RTP, precedence given is 5 otherwise some other precendence. But you may increase the precedence of the traffic from one particular host by configuring the COS value of 5 on the switchport it is configured.
For reference
Voice QoS: ToS-CoS Packet Marking for use with LLQ