This looks like the policy you have configured now. Can i have the policy that you have configured before for the service to run and did not work ? So basically certain services require elevated privileges to run and it could be run and it they require manual intervention to start them. This service that you are trying to run could be one such a service.
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Can you show us the requirement you have configured and the remediation configured for the same? I mean the way you were trying to do this before without the launch program remediation.
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Please call in the TAC front line using the phone numbers @ http://www.cisco.com/en/US/support/tsd_cisco_worldwide_contacts.html . They will help you create a case with TAC. Cheers.
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One thing that i can notice is that there is no DHCP allowed in the dACL. If PC does not get an IP, NAC Agent will definitely not pop up. However, this a candidate for a TAC case as this involves lot of things including but not limited to a problem in the network, switch configuration/capability to redirect, connectivity to the ISE, client issue etc.
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As Steve said, it is expected and AnyConnect does not support Fast Switching of users on the same machine. What is the issue with native wireless client? AFAIK, there are no compatibility issues as such.
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