Resolution
In the Protected Extensible Authentication Protocol (PEAP) MsChap V2, it is possible to configure two-password sign on as well as two usernames and passwords. You must have one set for Microsoft Windows and another for WLAN, but the WLAN username and passwords must be created under the Cisco Secure Access Control Software (ACS).
Refer to these documents for more information:
Problem Type
Configure / Configuration issues
Products
WLAN adapters (wireless card) / ACU (Aironet Client Utility)
Security Options
PEAP
ACS