Hi there,
Let me know if I am wrong, but it sounds like you are trying to run a nmap scan on a remote subnet? nmap require a target IP address, it is not possible for a scan to an IPv4 address to reveal any IPv6 addressing and vice versa.
At the very least it requires there is IPv6 connectivity to and from your host to the target subnet. However without a valid IPv6 prefix to scan, you would need to be on-link and running a packet capture looking for multicast traffic, this would reveal the IPv6 addressing.
cheers,
Seb.