depending on how you've deployed prime, you can use the compliance tool. Now, your question was is there any way to see the config. the compliance tool doesn't really do that, but you can set up a template that includes the baseline of how the switches should be set up, and will show any discrepancies when you run the template.
other than that, I don't think there's a way to automate this. I mean you could always view the config archive in prime, but you'd need forever and a day to audit a large number of switches.