Hi, I believe you can with the command 'ntp master' command. Here is the command reference. In your case, I would do this on the 6509.
ntp master
To configure the Cisco IOS software as a Network Time Protocol (NTP) master clock to which peers synchronize themselves when an external NTP source is not available, use the ntp master global configuration command. To disable the master clock function, use the no form of this command.