Hi,
I think the choice of cross stack EtherChannel on the Catalyst 3750 to connect to vPC on the Nexus 3000 seems like a reasonable approach.
I'm not sure how many links you intend to use, but it sounds like you have two 10GE links from each physical switch of the stack. If that's the case and you intend to connect 10 * 10GE links in the port-channel, remember that while you can configure up to 16 ports as members of a port-channel, only eight of the ports are in active mode. There will be two ports in standby mode.
The other point to note is that the Nexus supports IEEE 802.3ad Link Aggregation Control Protocol (LACP), whereas the Calalyst will support LACP and the Cisco proprietary Port Aggregation Protocol (PAgP). This shouldn't be a problem as long as you configure both the Nexus and Catalyst to use an LACP (channel-group <group> mode active) or static (channel-group <group> mode on) aggregate. I'd recommend using LACP.
Regards