Based on your daigram you dont need to configure VPC. Simple etherchannel/Portchannel is required. VPC is required when you are going to connecting the switch to two uplink different switches and want to form the bundle.
To have simplicity I would create two Port-Channel for your setup.
1- Port E3/45 &E4/45 to be part of 1 Port-Channel. 2- Port E3/46 & E4/46 to be part of 2nd port-channel.
HTH
Regards
Inayath
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