I think this is Happening by Default: you have a vswitch and a DVS, and 2 uplinks (defined in the Service Profile) ; therefore each Switch has one uplink.
You could simply migrate the uplink from the vswitch to the DVS.
However, it might be better to leave mgt and vmotion traffic on vswitch, and only VM traffic on DVS. if DVS is screwed up, you still have Access to ESXi.
This however would required to define e.g 4 Interfaces in the Service Profile; 2 for vswitch, 2 for DVS.