Thanks again Kirk,
From the Fabric Interconnects I was able to get the following info:
nic 1 - 00:25:B5:91:1A:8F - Fabric A veth757 (00-vNIC-A)
nic 2 - 00:25:B5:91:1B:8F - Fabric B veth758 (01-vNIC-B)
nic 3 - 00:25:B5:91:1A:9F - Fabric A veth759 (02-iSCSI-A)
nic 4 - 00:25:B5:91:1B:9F - Fabric B veth760 (03-iSCSI-A)
This seems to tally with the below info in UCS:

When I looked at the the vmnics in the ESXi 'configure management network' section it showed the following:
vmnic0 - (00:25:B5:91:1A:8F) status: connected
vmnic1 - (00:25:B5:91:1B:8F) status: connected
vmnic2 - (00:25:B5:91:1A:9F) status: iSCSIBootvSwitch
vmnic3 - (00:25:B5:91:1B:9F) status: connected
I chose vmnic0 for the management interface, assigned it the IP address and it worked! :)
The only slightly odd thing is that although the Nimble boot LUN allows multiple connections, ESXi seems to be only making one connection via vmnic2 (which is the UCS vNIC '02-iSCSI-A') - is this a deliberate policy from ESXi?