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Your forgetting the overhead requirements for hypervisor and storage controller will take away some of the total resources in the same way selection of storage replication of RF-2 or RF-3 effects your available storage capacity.
Charles,Yes the server will work standalone. First of all if the server was joined to UCSM then you'll need to follow the decommission procedure to remove it from UCSM and disassociate the service profile from the NIC card. If the server was physical...
