There are two phrases in PEAP. The first phrase is set up a TLS tunnel; so that the authentication server (i.e. radius server) can authenticate the supplicant in a secured tunnel. Please go to the following URL for the PEAP phrase:
http://www.cisco.com/en/US/partner/products/sw/secursw/ps2086/products_white_paper09186a008009256b.shtml#wp39068
If you use a Cisco AP, you can enable the following debugs:
1. debug radius authentication
2. debug dot11 aaa authenticator process
3. debug dot11 aaa authenticator state
4. debug dot11 aaa authenticator rxdata
5. debug dot11 aaa authenticator txdata
If you use IOS version 12.2(13)JA4 or earlier, please replace #2-5 by debug dot11 aaa all
Please be aware that the above debugs consumes a lot of CPU resource on the AP. I suggest you to run the debugs when there is only one wireless client trying to associate. Please go to the following URL about the debugs:
http://www.cisco.com/en/US/products/hw/wireless/ps430/products_tech_note09186a008024aa4f.shtml