Hello Carl,
a standard access list would indeed be sufficient to trigger the ISDN:
access-list 1 permit 10.0.0.0 0.255.255.255
dialer-list 1 protocol ip list 1
In your example you are using an extended access list (100), which requires a source and destination. If you want to use that, the configuration would look like this:
access-list 100 permit ip 10.0.0.0 0.255.255.255 any
dialer-list 1 protocol ip list 100
The effect is the same: outbound traffic from the 10.0.0.0/8 range will trigger the ISDN line...
HTH,
GP