The NCS and WLCs do not sync their data. You must refresh the config from the WLC in order to have the same configuration info. So when you are under configure controllers, on the drop down on the top right is an option to refresh the config from the WLC. You click that and then don't retain the old info when it prompts you.
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The attachement is hard to see... I beleive as long as you have the SSID defined in NCS, you can add that to the default-group. I tend to create everything on the WLC then refresh the config and delete the old.
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