@aleopoldie This is the relevant excerpt from the doc you provided
1+1+1 setup: One Catalyst Center appliance functions as your Main Site, a second appliance serves as your Recovery Site, and a third system (residing on a virtual machine) acts as your Witness Site. [end excerpt]
We don't conventionally call a single appliance, "a cluster". It's just an appliance at that point.
You are correct that each appliance at each DC will have it's own unique enterprise IP address configured.