You can upgrade to 64-bits but I don't see a need to, all you really need to do is iPXE boot the RSP5s (if not running any OS yet), install the optional packages (for 64-bit) and then in config mode 'load' the config from usb or copy the file to the router and apply it. You shouldn't have a problem migrating the config from 32-bit to 64-bit, very few commands were changed, if for some reason something doesn't apply the commit will fail and you can check 'show config failed' to see why, verify you have all the packages needed installed, try commit best-effort to apply everything that didn't fail and then figure out why something failed. But again I don't think you will run into an issue so long as you have installed the right packages.
Sam